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MHT CET Medical202625 April 2026Evening ShiftChemistryAldehydes and KetonesActual

When a mixture of an aldehyde and Fehling solution is boiled in hot water, a red precipitate is formed. Here the obtained red precipitate is of -

Options

  1. ACuprous oxide
  2. BCupric chloride
  3. CCuprous hydroxide
  4. DCupric sulphate

Correct answer

A. Cuprous oxide

Step-by-step solution

Fehling's solution is an alkaline solution of copper(II) sulfate complexed with tartrate ions. When an aliphatic aldehyde is heated with Fehling's solution, the aldehyde is oxidized to the corresponding carboxylate anion, and the cupric ions ( Cu²⁺ ) are reduced to cuprous oxide ( Cu₂O ). The chemical reaction is given by: R-CHO + 2Cu²⁺ + 5OH⁻ R-COO⁻ + Cu₂O + 3H₂O The Cu₂O (cuprous oxide) formed appears as a red precipitate. Answer: Cuprous oxide

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