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Aldehydes and Ketones — NEET UG Chemistry PYQs

484 previous year questions from Aldehydes and Ketones with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

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1

Base catalyzed aldol condensation occurs with

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2

Aromatic aldehydes are less reactive than the aliphatic aldehydes in nucleophilic addition reaction this is due to

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3

Identify a final product obtained when Pent-3-enenitrile is treated with AlH (i -Bu )₂ followed by acid hydrolysis.

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4

When a mixture of an aldehyde and Fehling solution is boiled in hot water, a red precipitate is formed. Here the obtained red precipitate is of -

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5

Which of the following reagents gives the same reduction product with propionaldehyde and acetone ?

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6

Which of the following statements regarding the haloform test is NOT correct?

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7

Which is the best reagent for the following conversion? CH ₃ -CH=CH-CH ₂ -CHO CH ₃ -CH=CH-CH ₂ -CH ₂ -OH

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8

Aldehydes containing at least one -hydrogen atom undergo a reaction in presence of dilute aq. NaOH to form -hydroxyl aldehyde. Identify the reaction.

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9

Which of the following reagents converts acid chloride to aldehyde selectively?

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10

An organic compound 'A' ( C ₃ H ₆ O ) gives a positive iodoform test but does not reduce Tollens' reagent. Identify the compound 'A':

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11

Which one of the following compounds, on reaction with hydrogen cyanide (HCN), gives an optically active cyanohydrin?

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12

What is metaldehyde?

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13

Which of the following reagents reacts with both aldehydes and ketones?

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14

Which of the following compounds will not undergo aldol condensation?

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15

Identify a catalyst used in Stephen reaction from the following.

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16

What is the product obtained when Pent-3-enenitrile is treated with DIBAL-H followed by acid hydrolysis?

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17

Which of the following undergoes Haloform reaction?

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18

Benzaldehyde is converted to benzyl alcohol by

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19

Which of the following reactions converts > C=O to > CH ₂ ? (A) Rosenmund's reaction (B) Aldol condensation (C) Clemmensen's reduction (D) Wolf-Kishner reduction Choose the correct

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20

aligned CH ₂= CH - CHO ? CH ₂= & CH & - CH ₂- OH aligned Suitable reagent for conversion of following reaction?

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21

Which of the following will not be formed when calcium acetate is distilled with calcium formate?

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22

In the reaction, The major product formed is

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23

Cannizzaro reaction is not shown by

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24

The product of acid hydrolysis of (P) and (Q) can be distinguished by

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25

Which of the following is crossed aldol product in the reaction? CH ₃ CHO + CH ₃ CH ₂ CHO [25^ C ] OH ⁻ ^ P '

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26

Choose the correct alkyne and reagents for the preparation of

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27

Clemmensen reduction of a ketone is carried out in the presence of which of the following?

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28

CH ₃ CHO + HCHO [ Heat ] Dil. NaOH A [ H ₃ O ⁺] HCN B The structure of compound B is

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29

The compound which is not formed during the dry distillation of a mixture of calcium formate and calcium acetate is

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30

Which of the following reagents converts both acetaldehyde and acetone to alkanes ?

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31

In which of the following pairs, both molecules possess dipole moment ?

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32

The reaction, C ₆ H ₅ CHO + CH ₃ COOC ₂ H ₅ C ₆ H ₅ CH = CHCOOC ₂ H ₅ , is called

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33

Which one of the following reactions is called Rosenmund reaction?

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34

Which of the following does not reduce Fehling's solution?

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35

When dihydroxy acetone reacts with ( HIO ₄ ), the product is/are

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36

The major organic product formed from the following reaction [ (ii) LiAlH ₄ (iii) H ₂ O ] (i) CH ₃ NH ₂ is

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37

CH ₃ CH ₂ C CH R butanone -2 . R is

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38

In the reaction of aldehydes and ketones with hydrogen cyanide (HCN), what is the role of the cyanide ion (CN-)?

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39

What role does concentrated alkali play in the Cannizzaro reaction?

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40

When is the dehydrogenation method suitable for preparing aldehydes and ketones?

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41

Which class of aldehydes does not respond to Fehling's test?

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42

What is the role of acid in the addition reaction of ammonia and its derivatives with aldehydes and ketones?

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43

What type of compounds are formed in the Aldol condensation reaction?

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44

What reagent is used in Tollens' test to detect aldehydes?

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45

Which aldehyde is commonly used to preserve biological specimens and in the production of bakelite?

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46

Give an example of a compound that adds fragrance to nature and is derived from vanilla beans.

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47

What is the purpose of using a catalyst in the Rosenmund reduction?

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48

What is the final product obtained after the hydrolysis of benzal chloride?

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49

In which type of solvents, such as benzene, ether, methanol, and chloroform, are aldehydes and ketones generally fairly soluble?

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50

What type of reaction is the addition of ammonia and its derivatives to aldehydes and ketones?

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51

Which functional group in aldehydes is responsible for the reaction with Tollens' reagent?

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52

What factor influences the position of the equilibrium in the reaction of sodium hydrogensulphite with aldehydes and ketones?

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53

What does the addition of sodium hydrogen sulphide form when it reacts with aldehydes and ketones?

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54

What is the name of the intermediate compound formed when aldehydes react with monohydric alcohol in the presence of dry hydrogen chloride?

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55

In addition to flavouring agents, for what other purpose are some families of aldehydes, ketones, and carboxylic acids manufactured, according to the paragraph?

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56

What heavy metal catalysts are commonly used in the dehydrogenation method for producing aldehydes and ketones?

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57

Besides sodium hypobromite, what other halogen reagent can be used for the haloform reaction to detect specific functional groups?

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58

Where does the equilibrium position generally lie when sodium hydrogen sulfite reacts with most aldehydes?

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59

What can benzylidene diacetate be hydrolyzed into, as mentioned in the paragraph?

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60

What are gem-dialkoxy compounds known as, which are formed when hemiacetals react with one more molecule of alcohol?

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61

Which of the following is NOT a common role of the carbonyl group in electrophilic substitution reactions?

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62

In what important processes of life do aldehydes, ketones, and carboxylic acids play a significant role?

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63

What is the primary difference in the oxidation reactions between aldehydes and ketones?

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64

Which type of reaction is the Rosenmund reduction classified as?

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65

What is the practical application of naturally occurring aldehydes and ketones mentioned in the paragraph?

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66

Why is the addition of hydrogen cyanide (HCN) to aldehydes and ketones catalysed by a base?

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67

What is the general name for the products of the Aldol condensation reaction?

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68

How can the hydrogen sulfite addition compound, formed by the reaction of sodium hydrogensulphite with aldehydes and ketones, be converted back to the original carbonyl compound?

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69

What is the result of the reduction of the carbonyl group of aldehydes and ketones with zinc-amalgam and concentrated hydrochloric acid?

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70

What does the Rosenmund reduction primarily involve?

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71

What type of reaction is involved in Tollens' test?

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72

What is the final product formed when an aldehyde reacts with Tollens' reagent?

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73

What is the colour change observed during a positive Tollens' test?

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74

Which compound, found in cinnamon, is known for its pleasant fragrance?

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75

How do the reactivity of aldehydes and ketones change with the number of alkyl groups attached to the carbonyl carbon?

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76

What role does the base play in the catalysis of the reaction between aldehydes/ketones and hydrogen cyanide (HCN)?

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77

How does dry hydrogen chloride affect the carbonyl compounds in the reaction with alcohols?

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78

Which reagent selectively reduces nitriles to imines in an alternative method?

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79

What type of cyclic products are formed when ketones react with ethylene glycol under similar conditions?

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80

Which lower members of aldehydes and ketones are mentioned as being miscible with water in all proportions?

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81

Which element is reduced to form a silver mirror in Tollens' test?

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82

What is the purpose of side chain chlorination followed by hydrolysis in the context of benzaldehyde production?

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83

What happens to the odour of aldehydes and ketones as the size of the molecule increases?

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84

What is the key factor that allows methanal, ethanal, and propanone to be miscible with water?

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85

Under what conditions are ketones generally oxidized?

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86

What is the outcome of treating a nitrile with a Grignard reagent followed by hydrolysis?

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87

What is the pH condition under which Fehling's test occurs?

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88

What happens to the aldehyde during Fehling's test?

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89

What is the visual indicator of a positive Fehling's test for an aldehyde?

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90

Why are aldehydes generally more reactive than ketones in nucleophilic addition reactions?

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91

What functional group characterises acyl halides?

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92

Why is the reaction involving aldehydes and ketones called Aldol condensation?

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93

What are the products of the reduction of aldehydes and ketones by sodium borohydride (NaBH 4 ) or lithium aluminium hydride (LiAlH 4 )?

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94

What is the common element in the functional groups found in amides and acyl halides?

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95

What is the source of salicylaldehyde, which contributes to the fragrance?

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96

What is the product obtained after the hydrolysis of imines produced in the Stephen reaction?

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97

What is the name of the reaction where aldehydes undergo self oxidation and reduction in the presence of concentrated alkali?

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98

In electrophilic substitution reactions, to which position on the aromatic ring does the carbonyl group typically direct the incoming electrophile?

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99

What is the chemical structure of the intermediate formed during the addition reaction of ammonia and its derivatives to aldehydes and ketones?

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100

How can acetals and ketals be converted back to the corresponding carbonyl compounds?

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101

Which type of reaction is exemplified by the addition of hydrogen cyanide (HCN) to aldehydes and ketones?

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102

In the product >C=N-Z, what does Z represent?

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103

Why do aldehydes and ketones generally have higher boiling points than hydrocarbons and ethers of comparable molecular masses?

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104

What is the result of the oxidation of ketones?

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105

What is the chemical symbol for the halogen group in acyl halides?

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106

What is the visual indicator of a positive Tollens' test for an aldehyde?

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107

What type of products are typically obtained in cross aldol condensation?

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108

What is the common name for acyl chloride?

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109

What is the outcome of the Cannizzaro reaction for aldehydes without α-hydrogen atoms?

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110

When hemiacetals react with one more molecule of alcohol, what type of compound is formed?

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111

What is the significance of the statement "miscible with water in all proportions" in the context of methanal, ethanal, and propanone?

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112

Which type of oxidising agents can convert aldehydes into carboxylic acids?

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113

Which halogen is commonly used in the haloform reaction to oxidize methyl ketones?

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114

What is one of the primary applications of aldehydes, ketones, and carboxylic acids in the food and pharmaceutical industries, as mentioned in the paragraph?

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115

What is the function of barium sulphate in the Rosenmund reduction?

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116

What happens to the aldehyde during Tollens' test?

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117

What happens to the aldol and ketol products in Aldol condensation?

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118

What is the term for the aldol condensation between two different aldehydes and/or ketones?

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119

What is the purpose of mixing Fehling solution A and Fehling solution B in equal amounts before the test?

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120

What is the intermediate compound formed when aldehydes react with monohydric alcohol in the presence of dry hydrogen chloride?

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