MHT CET Medical202625 April 2026Morning ShiftChemistryAldehydes and KetonesActual
Which of the following statements regarding the haloform test is NOT correct?
Options
- AEthanol exhibits this test.
- BIt is given by acetaldehyde.
- CIt is given by compounds containing methyl ketone group.
- DIt is given by benzaldehyde.
Correct answer
D. It is given by benzaldehyde.
Step-by-step solution
The haloform test is given by compounds containing a methyl ketone group ( CH₃-CO- ) or compounds that can be oxidized to a methyl ketone group under the reaction conditions, such as alcohols containing the CH₃-CH(OH)- group. Ethanol ( CH₃-CH₂-OH ) is oxidized to acetaldehyde ( CH₃-CHO ) by the halogen and alkali mixture, which then gives a positive haloform test. Acetaldehyde ( CH₃-CHO ) contains the CH₃-CO- group and gives a positive haloform test. Benzaldehyde ( C₆H₅-CHO ) does not contain a CH₃-CO- group and ca