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MHT CET 202624 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
24 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Aldehydes and Ketones

MHT CET 2026 · 24 April · Evening Shift · Chemistry · Aldehydes and Ketones

Which of the following reagents gives the same reduction product...

Which of the following reagents gives the same reduction product with propionaldehyde and acetone ?

Options

  1. ALiAlH4\text{LiAlH}_4
  2. BNi / H2\text{Ni}\ /\ \text{H}_2
  3. CNa-Hg / HCl\text{Na-Hg}\ /\ \text{HCl}
  4. DZn-Hg / Conc HCl\text{Zn-Hg}\ /\ \text{Conc HCl}

Correct answer

D. Zn-Hg / Conc HCl\text{Zn-Hg}\ /\ \text{Conc HCl}

Step-by-step solution

Propionaldehyde is CH3CH2CHOCH_3CH_2CHO and acetone is CH3COCH3CH_3COCH_3.

Reduction with LiAlH4LiAlH_4, Ni/H2Ni / H_2, or Na−Hg/HClNa-Hg / HCl converts propionaldehyde to 1-propanol (CH_3CH_2CH_2OH)andacetoneto2−propanol(CH3CH(OH)CH3) and acetone to 2-propanol (CH_3CH(OH)CH_3), which are different products.

Reduction with Zn−Hg/Conc.HClZn-Hg / Conc. HCl (Clemmensen reduction) reduces the carbonyl group to a methylene group. Thus, both propionaldehyde and acetone are reduced to propane (CH_3CH_2CH_3),givingthesameproduct.<br><br>Answer:Zn-Hg / Conc HCl), giving the same product.<br><br>Answer: \text{Zn-Hg}\ /\ \text{Conc HCl}
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