MHT CET 202623 AprilMorning Shift
- Exam
- MHT CET
- Year
- 2026
- Date
- 23 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Electrochemistry
MHT CET 2026 · 23 April · Morning Shift · Chemistry · Electrochemistry
What is standard decrease in Gibbs energy for the following cell?...
What is standard decrease in Gibbs energy for the following cell?
if E^{}^{\circ}\,\text{Al}^{+3}/\text{Al} = -1.66 V, E^{}^{\circ}\,\text{Cd}^{+2}/\text{Cd} = -0.40 V
if E^{}^{\circ}\,\text{Al}^{+3}/\text{Al} = -1.66 V, E^{}^{\circ}\,\text{Cd}^{+2}/\text{Cd} = -0.40 V
Options
- A kJ
- B kJ
- C kJ
- D kJ
Correct answer
C. kJ
Step-by-step solution
The standard cell potential is given by:
E^{}^{\circ}_{\text{cell}} = E^{}^{\circ}_{\text{cathode}} - E^{}^{\circ}_{\text{anode}}
E^{}^{\circ}_{\text{cell}} = -0.40 - (-1.66) = 1.26 \text{ V}
The half-cell reactions are:
Anode:
Cathode:
To balance the number of electrons, the overall reaction involves the transfer of electrons, so .
The standard Gibbs free energy change is:
\Delta G^{}^{\circ} = -n F E^{}^{\circ}_{\text{cell}}
\Delta G^{}^{\circ} = -6 \times 96500 \times 1.26
\Delta G^{}^{\circ} = -729540 \text{ J} = -729.54 \text{ kJ}
Answer: kJ
E^{}^{\circ}_{\text{cell}} = E^{}^{\circ}_{\text{cathode}} - E^{}^{\circ}_{\text{anode}}
E^{}^{\circ}_{\text{cell}} = -0.40 - (-1.66) = 1.26 \text{ V}
The half-cell reactions are:
Anode:
Cathode:
To balance the number of electrons, the overall reaction involves the transfer of electrons, so .
The standard Gibbs free energy change is:
\Delta G^{}^{\circ} = -n F E^{}^{\circ}_{\text{cell}}
\Delta G^{}^{\circ} = -6 \times 96500 \times 1.26
\Delta G^{}^{\circ} = -729540 \text{ J} = -729.54 \text{ kJ}
Answer: kJ