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MHT CET Medical202621 April 2026Evening ShiftChemistryHaloalkanes and HaloarenesActual

Which of the following compounds forms isopropyl cyanide?

Options

  1. ACH ₃ -CH ₂ -CH ₂ -I and alcoholic AgCN
  2. BCH ₃ -CHBr-CH ₃ and alcoholic KCN
  3. CCH ₃ -CHBr-CH ₃ and alcoholic AgCN
  4. DCH ₃ -CH ₂ -CH ₂ -Cl and alcoholic KCN

Correct answer

B. CH ₃ -CHBr-CH ₃ and alcoholic KCN

Step-by-step solution

Isopropyl cyanide has the structure CH ₃ -CH(CN)-CH ₃ . To obtain isopropyl cyanide, the starting alkyl halide must contain an isopropyl group, which is CH ₃ -CH(X)-CH ₃ . When an alkyl halide reacts with alcoholic KCN, the major product is an alkyl cyanide (nitrile). This is because KCN is predominantly ionic, providing free cyanide ions ( CN ⁻ ) in solution. Attack occurs preferentially through the carbon atom as the C-C bond formed is stronger than a C-N bond. When an alkyl halide reacts with alcoholic AgCN, the

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