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MHT CET 202622 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
22 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

MHT CET 2026 · 22 April · Evening Shift · Chemistry · Thermodynamics (C)

Determine the constant external pressure required to compress 2...

Determine the constant external pressure required to compress 22 mole of an ideal gas from volume 10.8 dm310.8\ \text{dm}^3 to 5.4 dm35.4\ \text{dm}^3 if the work obtained is 24602460 J.

Options

  1. A2.282.28 bar
  2. B1.141.14 bar
  3. C3.423.42 bar
  4. D4.564.56 bar

Correct answer

D. 4.564.56 bar

Step-by-step solution

Work done during compression against a constant external pressure is W=−PextΔVW = -P_{\text{ext}} \Delta V.

Given W=2460 JW = 2460 \text{ J}, V1=10.8 dm3V_1 = 10.8 \text{ dm}^3, V2=5.4 dm3V_2 = 5.4 \text{ dm}^3.

ΔV=5.4−10.8=−5.4 dm3=−5.4 L\Delta V = 5.4 - 10.8 = -5.4 \text{ dm}^3 = -5.4 \text{ L}.

Substituting the values:

2460 J=−Pext×(−5.4 L)2460 \text{ J} = -P_{\text{ext}} \times (-5.4 \text{ L})

Since 1 L bar=100 J1 \text{ L bar} = 100 \text{ J}, we have:

2460=Pext×5.4×1002460 = P_{\text{ext}} \times 5.4 \times 100

Pext=2460540=4.555 bar≈4.56 barP_{\text{ext}} = \dfrac{2460}{540} = 4.555 \text{ bar} \approx 4.56 \text{ bar}.

Answer: 4.564.56 bar
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