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MHT CET 202622 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
22 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

MHT CET 2026 · 22 April · Morning Shift · Chemistry · Thermodynamics (C)

Calculate the amount of work done in the oxidation of 1 mole of...

Calculate the amount of work done in the oxidation of 1 mole of HCl(g) at 127^{}^{\circ} C if
4 HCl(g)+O2(g)→2Cl2(g)+2H2O(g)4\,\text{HCl(g)} + \text{O}_2\text{(g)} \rightarrow 2\text{Cl}_2\text{(g)} + 2\text{H}_2\text{O(g)} ; [ R = 8.314 JK^{-1}mol−1mol^{-1}]

Options

  1. A831.4831.4 J
  2. B491.6491.6 kJ
  3. C1474.61474.6 J
  4. D1662.81662.8 J

Correct answer

A. 831.4831.4 J

Step-by-step solution

The given reaction is:

4HCl(g)+O2(g)→2Cl2(g)+2H2O(g)4\text{HCl(g)} + \text{O}_2\text{(g)} \rightarrow 2\text{Cl}_2\text{(g)} + 2\text{H}_2\text{O(g)}

For the oxidation of 44 moles of HCl\text{HCl}, the change in the number of gaseous moles is:

Δng=(2+2)−(4+1)=−1\Delta n_g = (2 + 2) - (4 + 1) = -1

For the oxidation of 11 mole of HCl\text{HCl}, the change in the number of gaseous moles is:

Δng=−14\Delta n_g = -\dfrac{1}{4}

The given temperature is T = 127^{}^{\circ}\text{C} = 127 + 273 = 400\text{ K}.

The work done is given by the formula:

W=−ΔngRTW = -\Delta n_g R T

Substituting the values:

W=−(−14)×8.314×400W = -\left(-\dfrac{1}{4}\right) \times 8.314 \times 400

W=8.314×100=831.4 JW = 8.314 \times 100 = 831.4\text{ J}

Answer: 831.4831.4 J
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