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NEET 2006
Exam
NEET
Year
2006
Subject
Chemistry
Chapter
Amines

NEET 2006 · Chemistry · Amines

In a set of reactions propionic acid yielded a compound 'd'. (CH_2...

In a set of reactions propionic acid yielded a compound 'd'. (\mathrm{CH}_2 \mathrm{CH}_2 \mathrm{COOH}\xrightarrow{\mathrm{SOCl}_2}{ }^{\prime} b^{\prime} \xrightarrow{\mathrm{NH}_3}{ }^{\prime} c^{\prime} \xrightarrow[\mathrm{Br}_2]{\mathrm{KOH}}{ }^{\prime} \mathrm{d}^{\prime}) The structure of 'd' would be:In a set of reactions propionic acid yielded a compound 'd'. (CH_2 CH_2 COOH SOCl_2 ^ b^ NH_3 ^ c^ [Br_2] KOH ^ d^ )In a set of reactions propionic acid yielded a compound 'd'. (CH_2 CH_2 COOH SOCl_2 ^ b^ NH_3 ^ c^ [Br_2] KOH ^ d^ )

Options

  1. ACH3CH2NH2\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2
  2. BCH3CH2CH2NH2\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{NH}_2
  3. CCH3CH2CONH2\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CONH}_2
  4. DCH3CH2NHCH3\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NHCH}_3

Correct answer

A. CH3CH2NH2\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2

Step-by-step solution

In a set of reactions propionic acid yielded a compound 'd'. (CH_2 CH_2 COOH SOCl_2 ^ b^ NH_3 ^ c^ [Br_2] KOH ^ d^ )
In a set of reactions propionic acid yielded a compound 'd'. (CH_2 CH_2 COOH SOCl_2 ^ b^ NH_3 ^ c^ [Br_2] KOH ^ d^ )
Related Theory When an amide is treated with bromine in an aqueous or ethanolic solution of sodium hydroxide, degradation of amide takes place leading to the formation of primary amine. This reaction is known as Hoffmann bromamide degradation reaction.
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