NEET 2006
- Exam
- NEET
- Year
- 2006
- Subject
- Chemistry
- Chapter
- Amines
NEET 2006 · Chemistry · Amines
Which of the following is more basic than aniline?
Which of the following is more basic than aniline?
Options
- Abenzylamine
- Bdiphenylamine
- Ctriphenylamine
- Dp-nitroaniline
Correct answer
A. benzylamine
Step-by-step solution
Benzyl amine is more basic than aniline because the benzyl group is an electron-donating group on account of the + I effect. So, it is capable of increasing the electron density of of the group. Thus, because of the higher electron density, the rate of donation of a free pair of electrons is increased, i.e., the basic character is higher. Phenyl and nitro groups are electron attractive groups, so they are able to decrease the electron density of of group. Hence, they are less basic than aniline.

A Caution Benzylamine has localised lone pair therefore it is more basic.
A Caution Benzylamine has localised lone pair therefore it is more basic.