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NEET 2005
Exam
NEET
Year
2005
Subject
Chemistry
Chapter
Chemical Equilibrium

NEET 2005 · Chemistry · Chemical Equilibrium

Equilibrium constants K_1 and K_2 for the following equilibria: are...

Equilibrium constants K1\mathrm{K}_1 and K2\mathrm{K}_2 for the following equilibria: Equilibrium constants K_1 and K_2 for the following equilibria: are related as:
are related as:

Options

  1. AK2=1/K12\mathrm{K}_2=1 / \mathrm{K}_1{ }^2
  2. BK2=K12\mathrm{K}_2=\mathrm{K}_1{ }^2
  3. CK2=1/K1\mathrm{K}_2=1 / \mathrm{K}_1
  4. DK2=K1/2\mathrm{K}_2=\mathrm{K}_1 / 2

Correct answer

A. K2=1/K12\mathrm{K}_2=1 / \mathrm{K}_1{ }^2

Step-by-step solution

K1=pNO2pNO⋅(pO2)1/2K2=(pNO)2⋅pO2(pNO2)2\mathrm{K}_1=\frac{p_{\mathrm{NO} 2}}{p_{\mathrm{NO}} \cdot\left(\mathrm{p}_{\mathrm{O} 2}\right)^{1 / 2}} \mathrm{K}_2=\frac{\left(p_{\mathrm{NO}}\right)^2 \cdot p_{\mathrm{O} 2}}{\left(\mathrm{p}_{\mathrm{NO} 2}\right)^2} takin square root on both sides in eq. 2. \begin{aligned} & \Rightarrow \sqrt{\mathrm{K}_2}=\frac{p_{\mathrm{NO}} \cdot\left(p_{\mathrm{O} 2}\right)^{1 / 2}}{p_{\mathrm{NO} 2}} \\ & \Rightarrow \sqrt{\mathrm{K}_2}=\frac{1}{\mathrm{~K}_1} \Rightarrow \mathrm{K}_2=\frac{1}{\mathrm{~K}_1^2} \end{aligned}
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