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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Electrochemistry

NEET 2026 · Chemistry · Electrochemistry

The standard electrode potential ( E^ ) for the half-cell reaction...

The standard electrode potential (E∘E^\circ) for the half-cell reaction Fe3++e−→Fe2+\text{Fe}^{3+}+e^-\rightarrow\text{Fe}^{2+} at 298298 K is
(Given: E∘(Fe3+/Fe)=−0.04E^\circ(\text{Fe}^{3+}/\text{Fe})=-0.04 V and E∘(Fe2+/Fe)=−0.44E^\circ(\text{Fe}^{2+}/\text{Fe})=-0.44 V at 298298 K)

Options

  1. A+0.92+0.92 V
  2. B+0.40+0.40 V
  3. C+0.76+0.76 V
  4. D−0.48-0.48 V

Correct answer

C. +0.76+0.76 V

Step-by-step solution

The given half-cell reactions are:

Fe3++3e−→Fe\text{Fe}^{3+} + 3e^- \rightarrow \text{Fe}, E1∘=−0.04E^\circ_1 = -0.04 V
ΔG1∘=−n1FE1∘=−3×F×(−0.04)=0.12F\Delta G^\circ_1 = -n_1FE^\circ_1 = -3 \times F \times (-0.04) = 0.12F

Fe2++2e−→Fe\text{Fe}^{2+} + 2e^- \rightarrow \text{Fe}, E2∘=−0.44E^\circ_2 = -0.44 V
ΔG2∘=−n2FE2∘=−2×F×(−0.44)=0.88F\Delta G^\circ_2 = -n_2FE^\circ_2 = -2 \times F \times (-0.44) = 0.88F

The required half-cell reaction is:
Fe3++e−→Fe2+\text{Fe}^{3+} + e^- \rightarrow \text{Fe}^{2+}

This reaction can be obtained by subtracting the second reaction from the first reaction:
ΔG3∘=ΔG1∘−ΔG2∘\Delta G^\circ_3 = \Delta G^\circ_1 - \Delta G^\circ_2

−1×F×E3∘=0.12F−0.88F-1 \times F \times E^\circ_3 = 0.12F - 0.88F

−FE3∘=−0.76F-FE^\circ_3 = -0.76F

E3∘=+0.76E^\circ_3 = +0.76 V

Answer: +0.76+0.76 V
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