NEET 2022
- Exam
- NEET
- Year
- 2022
- Subject
- Chemistry
- Chapter
- Electrochemistry
NEET 2022 · Chemistry · Electrochemistry
Find the emf of the cell in which the following reaction takes...
Find the emf of the cell in which the following reaction takes place at
(Given that at )
Options
- A
- B
- C
- D
Correct answer
B.
Step-by-step solution
Given reaction:
Applying Nernst equation we have:
Active mass of solid is taken to be unity so \left[Ni\left(s\right)\right] = \left[Ag\left(s\right)\right] = 1{E}_{\left(cell\right)} = {E}_{\left(cell\right)}^{0} - \dfrac{0.059}{n}log\dfrac{\left[N{i}^{2 +}\right]}{{\left[A{g}^{+}\right]}^{2}}= 1.05 - \dfrac{0.0591}{2}log\dfrac{\left(0.001\right)}{{\left(0.001\right)}^{2}}= 1.05 - 0.0295\log (1\times {10}^{3} )= 1.05 - 0.0295 \times 3= 0.9615V0 . 9615VE{°}_{cell} = 1 . 05VinplaceofE{°}_{cell} = 10 . 5V$ as given in NEET 2022 paper.