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NEET 2018
Exam
NEET
Year
2018
Subject
Chemistry
Chapter
Electrochemistry

NEET 2018 · Chemistry · Electrochemistry

Consider the change in oxidation state of Bromine corresponding to...

Consider the change in oxidation state of Bromine corresponding to different emf values, as shown in the diagram below:
Consider the change in oxidation state of Bromine corresponding to different emf values, as shown in the diagram below:
Then, what is the species undergoing disproportionation?

Options

  1. ABr2\text{B}{\text{r}}_{2}
  2. BHBrO\text{HBr}\text{O}
  3. CBrO4−\text{Br}{\text{O}}_{4}^{-}
  4. DBrO3−\text{Br}{\text{O}}_{3}^{-}

Correct answer

B. HBrO\text{HBr}\text{O}

Step-by-step solution

Calculate Ecello{E}_{cell}^{o} corresponding to each compound undergoing disproportionation reaction. The reaction for which Ecello{E}_{cell}^{o} comes out +ve is spontaneous.

HBrO→Br2Eo=1.595,SRP(Cathode)\text{HBrO} \to \text{B}{\text{r}}_{2}{\text{E}}^{\text{o}} = 1.595, \text{S}\text{R}\text{P}\left(\text{Cathode}\right)
2HBrO→Br2+BrO3−2\text{HBrO} \to \text{B}{\text{r}}_{2} + \text{B}\text{r}{\text{O}}_{3}^{-}
Ecello={\text{E}}_{\text{c}\text{e}\text{l}\text{l}}^{\text{o}} = SRP (cathode) - SRP (Anode)

=1.595−1.5= 1.595 - 1.5

=0.095V= 0 .095 V

Ecello>0⇒ΔGo<0{\text{E}}_{\text{cell}}^{\text{o}} > 0 ⇒ \Delta{\text{G}}^{o} < 0 [spontaneous]
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