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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Hydrocarbons

NEET 2026 · Chemistry · Hydrocarbons

For the following reaction sequence, choose the correct option

For the following reaction sequence, choose the correct option
For the following reaction sequence, choose the correct option

Options

  1. ABoth P\text{P} and Q\text{Q} are carbonyl compounds.
  2. BIf P\text{P} is the sodium salt of a carboxylic acid, Q\text{Q} is a primary alcohol.
  3. CP\text{P} and Q\text{Q} are aromatic compounds.
  4. DIf P\text{P} gives a carboxylic acid on acidification, Q\text{Q} gives a poisonous gas on exposure to air and light.

Correct answer

D. If P\text{P} gives a carboxylic acid on acidification, Q\text{Q} gives a poisonous gas on exposure to air and light.

Step-by-step solution

The first step is the Friedel-Crafts acylation of benzene with acetyl chloride (CH3COCl\text{CH}_3\text{COCl}) and anhydrous AlCl3\text{AlCl}_3, which produces acetophenone (C6H5COCH3\text{C}_6\text{H}_5\text{COCH}_3).

The second step is the haloform reaction. Acetophenone has a methyl ketone group and reacts with sodium hypochlorite (NaOCl\text{NaOCl}) to form sodium benzoate (C6H5COONa\text{C}_6\text{H}_5\text{COONa}) and chloroform (CHCl3\text{CHCl}_3).

Thus, the products P\text{P} and Q\text{Q} are sodium benzoate and chloroform.

Sodium benzoate (P\text{P}) on acidification yields benzoic acid (C6H5COOH\text{C}_6\text{H}_5\text{COOH}).

Chloroform (Q\text{Q}) on exposure to air and light oxidizes to form phosgene (COCl2\text{COCl}_2), a highly poisonous gas, according to the reaction:
2CHCl3+O2→light2COCl2+2HCl2\text{CHCl}_3 + \text{O}_2 \xrightarrow{\text{light}} 2\text{COCl}_2 + 2\text{HCl}

Therefore, if P\text{P} gives a carboxylic acid on acidification, Q\text{Q} gives a poisonous gas on exposure to air and light.

Answer: If P\text{P} gives a carboxylic acid on acidification, Q\text{Q} gives a poisonous gas on exposure to air and light.
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