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NEET 2005
Exam
NEET
Year
2005
Subject
Chemistry
Chapter
Hydrocarbons

NEET 2005 · Chemistry · Hydrocarbons

Which one of the following alkenes will react faster with H_2 under...

Which one of the following alkenes will react faster with H2\mathrm{H}_2 under catalytic hydrogenation conditions?Which one of the following alkenes will react faster with H_2 under catalytic hydrogenation conditions?Which one of the following alkenes will react faster with H_2 under catalytic hydrogenation conditions?Which one of the following alkenes will react faster with H_2 under catalytic hydrogenation conditions?Which one of the following alkenes will react faster with H_2 under catalytic hydrogenation conditions?

Options

  1. AHow are good yields of alkyl iodides (R—I) obtained?
  2. BHow are good yields of alkyl iodides (R—I) obtained?
  3. CHow are good yields of alkyl iodides (R—I) obtained?
  4. DHow are good yields of alkyl iodides (R—I) obtained?

Correct answer

A. How are good yields of alkyl iodides (R—I) obtained?

Step-by-step solution

Due to steric hinderence, hyperconjugation and heat of hydrogenation, reactivity of alkenes can be shown as:H2C=CH2>R−CH=CH2>R−CH=CH−R>R2C=CH2>R2C=CHR>R2C=CR2.\begin{aligned}& \mathrm{H}_{2} \mathrm{C}=\mathrm{CH}_{2}>\mathrm{R}-\mathrm{CH}=\mathrm{CH}_{2}> \\ & \mathrm{R}-\mathrm{CH}=\mathrm{CH}-\mathrm{R}> \mathrm{R}_{2} \mathrm{C}=\mathrm{CH}_{2}> \\ & \mathrm{R}_{2} \mathrm{C}=\mathrm{CHR}>\mathrm{R}_{2} \mathrm{C}=\mathrm{CR}_{2} . \end{aligned}Related Theory The relative rates of hydrogenation decrease with the increase of steric hindrance. In order of stability of alkene, most stable the alkene slowly it gives the product.
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