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NEET 2012
Exam
NEET
Year
2012
Subject
Chemistry
Chapter
Hydrocarbons

NEET 2012 · Chemistry · Hydrocarbons

Which of the following reagents will be able to distinguish between...

Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne?

Options

  1. ANaNH2\mathrm{NaNH}_2
  2. BHCl\mathrm{HCl}
  3. CO2\mathrm{O}_2
  4. DBr2\mathrm{Br}_2

Correct answer

A. NaNH2\mathrm{NaNH}_2

Step-by-step solution

NaNH2\mathrm{NaNH}_2 is used to distinguish between 1-butyne and 2-butyne. \begin{aligned} &\begin{array}{r} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{C} \equiv \mathrm{CH} \stackrel{\mathrm{NaNH}_2}{\longrightarrow} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{C} \equiv \mathrm{CNa} \\ +\frac{1}{2} \mathrm{H}_2 \uparrow \end{array}\\ &\mathrm{CH}_3-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_3 \stackrel{\mathrm{NaNH}_2}{\longrightarrow} \text{ No reaction } \end{aligned}$$$
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