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NEET2015Chemistryp Block Elements (Group 13 & 14)Actual

The stability of +1 oxidation state among Al, Ga, In and Tl increases in the sequence:

Options

  1. AG a < I n < A l < T l
  2. BA l < G a < I n < T l
  3. CT l &#60; I n &#60; G a &#60; Al
  4. DI n < T l < G a < A l

Correct answer

B. A l < G a < I n < T l

Step-by-step solution

The inert-pair effect is the tendency of the two electrons in the outermost atomic-s orbital to remain unshared in compounds of post-transition elements. Inert-pair effect is seen in the elements of 13th,14th, 15th and 16th groups. Due to the inert-pair effect elements down the group exhibit oxidation state which is 2 units lesser than the elements above them. Stability of +1 oxidation state due to inert pair effect is in the order A l &#60; G a &#60; I n &#60; T l

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