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NEET 2013
Exam
NEET
Year
2013
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

NEET 2013 · Chemistry · p Block Elements (Group 13 & 14)

Which of these is not a monomer for a high molecular mass silicone...

Which of these is not a monomer for a high molecular mass silicone polymer?Which of these is not a monomer for a high molecular mass silicone polymer?

Options

  1. AMeSiCl3\mathrm{MeSiCl}_3
  2. BMe2SiCl2\mathrm{Me}_2 \mathrm{SiCl}_2
  3. CMe3SiCl\mathrm{Me}_3 \mathrm{SiCl}
  4. DPhSiCl3\mathrm{PhSiCl}_3

Correct answer

C. Me3SiCl\mathrm{Me}_3 \mathrm{SiCl}

Step-by-step solution

Me3SiCl\mathrm{Me}_3 \mathrm{SiCl} is not a monomer for a high molecular mass silicone polymer because it generates Me3SiOH\mathrm{Me}_3 \mathrm{SiOH} when subjected to hydrolysis which contains only one reacting site. Hence, the polymerisation reaction stops just after first step. Which of these is not a monomer for a high molecular mass silicone polymer?
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