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NEET2024Chemistryp Block Elements (Group 15, 16, 17 & 18)Actual

Given below are two statements: Statement I: The boiling point of hydrides of Group 16 elements follow the order H ₂ O H ₂ Te H ₂ Se H ₂ ~S . Statement II: On the basis of molecular mass, H ₂ O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H -bonding in H ₂ O , it has higher boiling point. In the light of the above statements, choose the correct answe

Options

  1. ABoth Statement I and Statement II are false
  2. BStatement I is true but Statement II is false
  3. CStatement I is false but Statement II is true
  4. DBoth Statement I and Statement II are true

Correct answer

D. Both Statement I and Statement II are true

Step-by-step solution

Statement I is correct, because boiling point of hydrides of group 16 follows the order H ₂ O H ₂ Te H ₂ Se H ₂ ~S . Statement II due to intermolecular H -bonding H ₂ O shows higher boiling point than respective hydrides of group 16. (Both Statement are true) Order from H ₂ Te to H ₂ ~S is due to decreasing molar mass.

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