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NEET p Block Elements (Group 15, 16, 17 & 18) PYQs with Solutions

1,072 previous year questions from p Block Elements (Group 15, 16, 17 & 18) (NEET UG Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

1,072 questionsChemistry2001–2026Answers + solutions

About p Block Elements (Group 15, 16, 17 & 18) PYQs

p Block Elements (Group 15, 16, 17 & 18) has 1,072 previous year questions in the Quantrex Academy NEET UG Chemistry bank. The 220 questions in this list come from NEET (106), AIIMS (79) and JIPMER (35), spanning 2001 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 2
  • 2025: 2
  • 2024: 5
  • 2023: 2
  • 2022: 4
  • 2021: 3
  • 2020: 3
  • 2019: 17
  • 2018: 16
  • 2017: 6
  • 2016: 14
  • 2015: 7

p Block Elements (Group 15, 16, 17 & 18) questions with solutions

1

Identify the incorrect statement from the following :

NEET 2026 Solution
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2

Given below are two statements: Statement-I : Heating NaCl with concentrated H _2 SO _4 and MnO _2 results in oxidation of Mn. Statement-II : Heating NaI with concentrated H _2 SO

NEET 2026 Solution
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3

Given below are two statements: Statement I : Like nitrogen that can form ammonia, arsenic can form arsine. Statement II : Antimony cannot form antimony pentoxide. In the light of

NEET 2025 Solution
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4

Match List - I with List-II List-I List-II A. XeO_3 I. sp^3 d, linear B. XeF_2 II. sp^3 ; pyramidal C. XeOF_4 III. sp^3 d³ ; distorted octahedral D. XeF_6 IV. sp^3 d² ; square

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5

Among Group 16 elements, which one does NOT show -2 oxidation state?

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6

Identify the incorrect statement.

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7

The products A and B obtained in the following reactions, respectively, are aligned & 3 ROH+PCl_3 arrow 3 RCl+A & ROH+PCl_5 arrow RCl+HCl+B aligned

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8

Given below are two statements: Statement I: The boiling point of hydrides of Group 16 elements follow the order H_2 O _2 Te _2 Se _2 ~S . Statement II: On the basis of molecular

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9

Identify the incorrect statement from the following:

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10

Match List-I with List-II List-I(Oxo acids of Sulphur) List-II(Bonds) A Peroxodisulphuric acid I Two S-OH, Four S=O, One S-O-S B Sulphuric acid II Two S-OH, One S=O C

NEET 2023 Solution
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11

Match list-I with List-II : List - I List - II A. Coke I. Carbon atoms are sp ^ 3 hybridised B. Diamond II. Used as dry lubricants C. Fullerene III. Used as a reducing agent D.

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12

Flourine is a stronger oxidising agent than chlorine because : (a) F-F bond has a low enthalpy of dissociation. (b) Flouride ion (F^ - ) has high hydration enthalpy (c) Electron

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13

Choose the correct statement:

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14

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R) . Assertion (A) : ICl is more reactive than I _ 2 . Reason (R) : I - Cl

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15

Which of the following reactions is a part of the large scale industrial preparation of nitric acid?

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16

Statement I: Acid strength increases in the order given as HF Statement II: As the size of the elements F, Cl, Br, I increases down the group, the bond strength of HF, HCl HBr and

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17

In which one of the following arrangements the given sequence is not strictly according to the properties indicated against it?

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18

Noble gases are named because of their inertness towards reactivity. Identify an incorrect statement about them.

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19

Match the compounds of Xe in column I with the molecular structure in column II. Column-I Column-II (a) XeF _ 2 (p) Square planar (b) XeF _ 4 (q) Linear (c) XeO _ 3 (r) Square

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20

Which of the following oxoacid of sulphur has – O – O – linkage?

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21

On electrolysis of dil. sulphuric acid using Platinum (Pt) electrode, the product obtained at anode will be

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22

Strong oxidising agent used in purification of water is

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23

Assertion : Pure N_2 is obtained from Ba(N_3)_2 but not from (NH_4)_2 Cr_2 O_7 . Reason : On decomposition, (NH_4)_2 Cr_2 O_7 gives O_2 gas.

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24

How is ammonia generally manufactured in large scale?

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25

In dimer of phosphorus pentoxide, in what order number of P-P, P=O and P-O-P bonds are there?

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26

Which of the following reacts most slowly with nitric acid?

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27

Yellow colour of chlorine water fades because

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28

Which will release NH_3 on reaction with NaOH ?

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29

In which of the following, oxidation state of phosphorous is +3 ?

JIPMER 2019 Solution
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30

Which of the following rare gas is the abundant in air?

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31

Which one of the following nitro compound does not react with nitrous acid?

JIPMER 2019 Solution
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32

A compound ' X^ upon reaction with H_2 O produced a colourless gas ' Y ' with rotten fish smell. Gas ' Y ' is absorbed in a solution of CuSO_4 to give Cu_3 P_2 as one of the

NEET 2019 Solution
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33

Which of the following oxoacids of phosphorus has strongest reducing property?

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34

Identify the correct formula of oleum from the following

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35

The number of moles of hydrogen molecules required to produce 20 moles of ammonia through Haber’s process is:

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36

Which is the correct thermal stability order for H _ 2 E(E = O, S, Se, TeandPo) ?

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37

Match the Xenon compounds in Column-I with its structure in Column-II and assign the correct code: Column-I Column-II (a) Xe F _ 4 (i) pyramidal (b) Xe F _ 6 (ii) square planar

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38

Match the following: (a) Pure nitrogen (i) Chlorine (b) Haber process (ii) Sulphuric acid (c) Contact process (iii) Ammonia (d) Deacon’s process (iv) Sodium azide or Barium

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39

Assertion : Pure N_2 is formed from Ba(N_3)_2 . Reason : Thermal decomposition of NaN_3 is used to inflate the air bags used for safety devices in some cars.

AIIMS 2018 Solution
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40

Which of the following statements is incorrect?

AIIMS 2018 Solution
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41

Which of the following is true for N_2 O_5 ?

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42

Assertion : F_2 and Cl_2 when passed through water, F_2 is more reactive. Reason : F_2 is most electronegative.

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43

Assertion : HCOOH reacts with H_2 SO_4 to form CO. Reason : H_2 SO_4 is a mild oxidising agent.

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44

Assertion : O_2 ~F_2 converts Pu to PuF_6 . Reason : O_2 ~F_2 is used to remove unreacted Pu from nuclear reaction.

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45

Assertion : O_3 has higher boiling point than O_2 . Reason : O_3 is allotrope of oxygen.

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46

Assertion : Brown ring test is not valid for Fe^ +3 ion. Reason : Because NO_3^ - ion first gets converted into NO_2^ - ion.

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47

Which of the following contains atleast one lone pair in all of its halides?

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48

Assertion : Red phosphorus on heating changes its colour into black. Reason : Black phosphorus contains P_4 units.

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49

Which of the following is correct statement?

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50

Xenon hexafluoride reacts with silica to form a xenon compound X . The oxidation state of xenon in X is

JIPMER 2018 Solution
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51

Among the following, the correct formula of Marshall's acid is

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52

Which of the following chemicals are used to manufacture methyl isocyanate that caused "Bhopal tragedy"? (i) Methylamine (ii) Phosgene (iii) Phosphine (iv) Dimethylamine

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53

The correct order of N - compounds in its decreasing order of oxidation states is

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54

Which of the following statements is not true for halogens?

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55

Assertion : Hydrides of group-16 elements show volatility in the order: H_2 O>H_2 ~S>H_2 Se>H_2 Te Reason : Electronegativity of group-16 elements increases down the group from

AIIMS 2017 Solution
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56

Which of the following oxoacids of phosphorus is a reducing agent and a monobasic acid as well?

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57

In which of the following compounds, sulphur show maximum oxidation number?

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58

Sulphur reacts with chlorine in 1: 2 ratio and forms X . Hydrolysis of X gives a sulphur compound Y . The hydridisation of central atom in the anion Y is

JIPMER 2017 Solution
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59

Among the following compounds, which will produce POCl_3 with PCl_5 .

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60

In which pair of ions do both the species contain S - S bond?

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61

Large difference in boiling points is observed in

AIIMS 2016 Solution
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62

Assertion : Charcoal is used in separation of noble gases. Reason: Charcoal has porous structure.

AIIMS 2016 Solution
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63

Chlorine oxidises sodium thiosulphate to form

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64

The true statement for the acids of phosphorus, H_3 PO_2, H_3 PO_3 and H_3 PO_4 is

AIIMS 2016 Solution
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65

When excess of NaOH solution is added to aqueous solution of iodine, the colour of solution becomes

JIPMER 2016 Solution
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66

Consider the reaction, H_2+X_2 2 H X , where X is halogen. The reactivity of halogens decrease in the order of

JIPMER 2016 Solution
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67

Anhydrous mixture of KF and HF contain which types of ions?

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68

Choose the incorrect statement about noble gas?

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69

Hot concentrated sulphuric acid is a moderately strong oxidizing agent. Which of the following reactions does not show oxidizing behaviour?

NEET 2016 Solution
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70

Among the following, the correct order of acidity is:

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71

Identify the correct statement from the statements given below.

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72

The product obtained as a result of a reaction of nitrogen with Ca C _ 2 is:

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73

Which of the following fluoro-compounds is most likely to behave as a Lewis base?

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74

When copper is heated with conc. HN O _ 3 it produces:

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75

XeF_6 on complete hydrolysis produces

AIIMS 2015 Solution
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76

Tincture of iodine is

AIIMS 2015 Solution
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77

aligned & SF_4 Hydrolysis X+Y & X+H_2 ~S Z aligned Here, Z is

JIPMER 2015 Solution
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78

Which of the statement given below is incorrect?

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79

The variation of the boiling points of the hydrogen halides is in the order HF > HI > HBr > HCl . Which of the following option explains the higher boiling point of hydrogen

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80

Strong reducing behaviour of H _ 3 P O _ 2 is due to:

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81

Nitrogen dioxide and sulphur dioxide have some properties in common. Which property is shown by one of these compounds, but not by the other?

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82

Rhombic sulphur dissolves best in

AIIMS 2014 Solution
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83

Enrichment of U^ 235 is done by

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84

Which halogen forms only one oxoacid (HOX) ?

AIIMS 2014 Solution
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85

Assertion : Al becomes passive in conc. HNO_3 . Reason: Conc. HNO_3 has no action on aluminium metal.

AIIMS 2014 Solution
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86

Assertion: Chloroform is stored in dark coloured bottles. Reason: Chronic chloroform exposure may cause damage to liver and kidneys.

AIIMS 2014 Solution
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87

Assertion : H_3 PO_3 is dibasic acid. Reason: Two hydrogen atoms are directly attached to the P.

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88

Which of the following is not correct?

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89

Acidity of diprotic acids in aqueous solutions increases in the order:

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90

(a) H _ 2 O _ 2 + O _ 3 → H _ 2 O + 2 O _ 2 (b)H _ 2 O _ 2 + A g _ 2 O → 2Ag + H _ 2 O + O _ 2 Role of hydrogen peroxide in the above reactions is respectively:

NEET 2014 Solution
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91

Which of the following statement is not true for hydrolysis of XeF_6 ?

AIIMS 2013 Solution
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92

Assertion : Phosphoric acid has no reducing properties. Reason : Phosphoric acid does not contain P-H bonds.

AIIMS 2013 Solution
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93

When Br_2 is treated with aqueous solutions of NaF, NaCl, NaI separately

JIPMER 2013 Solution
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94

Which of the following is the increasing order of enthalpy of vaporization?

JIPMER 2013 Solution
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95

Which of the following structure is similar to graphite?

NEET 2013 Solution
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96

Which of the following does not give oxygen on heating?

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97

How many P=O bond present in (HPO_3)_3 ?

AIIMS 2012 Solution
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98

N-N bond length is minimum in

AIIMS 2012 Solution
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99

Assertion : Fluorine is a stronger oxidizing agent than iodine. Reason : Fluorine has greater electronegativity than iodine.

AIIMS 2012 Solution
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100

Assertion : Cl_2 gas bleaches the articles permanently. Reason : Cl_2 is a strong reducing agent.

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101

Which of the following is the correct statement for PH_3 ?

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102

Assertion : H_3 PO_2 has strong reducing property but H_3 PO_4 does not. Reason : P-OH bond present in H_3 PO_4 .

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103

Which of the following statements is not valid for oxoacids of phosphorus?

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104

When Cl_2 gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from

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105

Sulphur trioxide can be obtained by which of the following reaction

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106

Iodine oxidises sodium borohydride to give

AIIMS 2011 Solution
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107

PCl_3 on hydrolysis gives fumes of

AIIMS 2011 Solution
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108

Best method to form aromatic iodide is

AIIMS 2011 Solution
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109

First compound of Xe synthesized was

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110

Assertion : Helium is used in diving apparatus. Reason : Solubility of helium is less in blood.

AIIMS 2011 Solution
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111

Which of the following fluorides does not exist?

JIPMER 2011 Solution
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112

Which will liberate bromine from a solution of potassium bromide?

JIPMER 2011 Solution
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113

In which of the following, NH_3 is not used?

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114

Bromine is added to cold dilute aqueous solution of NaOH . The mixture is boiled. Which of the following statements is not true?

AIIMS 2010 Solution
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115

Assertion : PCl_5 is covalent in gaseous and liquid states but ionic in solid state. Reason : PCl_5 in solid state consists of tetrahedral PCl_4^ + cation and octahedral PCl_6^

AIIMS 2010 Solution
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116

Assertion : Helium has the highest value of ionisation energy among all the elements known. Reason : Helium has the highest value of electron affinity among all the elements known.

AIIMS 2010 Solution
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117

The phosphate of a metal has the formula M HPO_4 . The formula of its chloride would be

AIIMS 2010 Solution
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118

In the electronic structure of H_2 SO_4 , the total number of unshared electrons is

JIPMER 2010 Solution
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119

Oxidation states of P in H_4 P_2 O_5, H_4 P_2 O_6 , H_4 P_2 O_7 , are respectively

NEET 2010 Solution
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120

Match List I (substances) with List II (processes employed in the manufacture of the substances) and select the correct option.

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