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NEET 2023
Exam
NEET
Year
2023
Subject
Chemistry
Chapter
Solid State

NEET 2023 · Chemistry · Solid State

A compound is formed by two elements A and B. The element B forms...

A compound is formed by two elements A and B. The element B forms cubic close packed structure and atoms of A occupy 13\dfrac{1}{3} of tetrahedral voids. If the formula of the compound is AxBy{A}_{x}{B}_{y}, then the value of x+yx + y is in option

Options

  1. A22
  2. B55
  3. C44
  4. D33

Correct answer

B. 55

Step-by-step solution

The number of effective atoms per unit cell in the cubic close packed arrangement is 4. Hence, there are four atoms of BB per unit cell. In cubic close packed arrangement, there are two tetrahedral voids per atom. So, eight tetrahedral voids are possible. Given that 1/31 / 3 of tetrahedral voids are occupied. Hence, the possible formula is

A83B4A\dfrac{8}{3}{B}_{4} and the simplest formula is A8B12≡A2B3{A}_{8}{B}_{12} ≡ {A}_{2}{B}_{3}.

So, x=2 and y=3x = 2 \text{ and } y = 3

⇒x+y=5⇒ x + y = 5

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