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NEET 2020
Exam
NEET
Year
2020
Subject
Chemistry
Chapter
Solutions

NEET 2020 · Chemistry · Solutions

If 8g of a non-electrolyte solute is dissolved in 114g of n -...

If 8g8g of a non-electrolyte solute is dissolved in 114g114g of n−n -octane to reduce its vapour pressure to 8080 % , the molar mass (in gmol−1g{mol}^{- 1}) of the solute is [Given that molar mass of n-octane is 114gmol−1114g{mol}^{- 1}]

Options

  1. A4040
  2. B6060
  3. C8080
  4. D2020

Correct answer

A. 4040

Step-by-step solution

Assuming dilute solution,
P0−PsPs≈P0−PsP0=nsolutensolvent\dfrac{{P}_{0} - {P}_{s}}{{P}_{s}} \approx \dfrac{{P}_{0} - {P}_{s}}{{P}_{0}} = \dfrac{{n}_{\text{solute}}}{{n}_{\text{solvent}}}
Let P0=100,{P}_{0} = 100, V.P reduced to 8080 % , ∴ {P}_{s} = 80
100−80100=8/m114/114\dfrac{100 - 80}{100} = \dfrac{8 / m}{114 / 114}
m=40m = 40 g/mol.
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