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NEET 2021
Exam
NEET
Year
2021
Subject
Chemistry
Chapter
Solutions

NEET 2021 · Chemistry · Solutions

The correct option for the value of vapour pressure of a solution...

The correct option for the value of vapour pressure of a solution at 45ºC45 º C with benzene to octane in molar ratio 3:23: 2 is:

[At 45°C45 ° C vapour pressure of benzene is 280mmHg280mmHg and that of octane is 420mmHg.420mmHg . Assume Ideal gas]

Options

  1. A160mm160mm of HgHg
  2. B168mm168mm of HgHg
  3. C336mm336mm of HgHg
  4. D350mm350mm of HgHg

Correct answer

C. 336mm336mm of HgHg

Step-by-step solution

Given: PB°=280mm{P}_{B} ° = 280mm of Hg,Po°=420mmHg, {P}_{o} ° = 420mm of HgHg

XB=35{X}_{B} = \dfrac{3}{5} and Xo=25{X}_{o} = \dfrac{2}{5}

We know that according to Raoult's Law

PT=XBPB°+XoPo°=35×280+25×420=336mm{P}_{T} = {X}_{B}{P}_{B}^{°} + {X}_{o}{P}_{o}^{°} = \dfrac{3}{5} \times 280 + \dfrac{2}{5} \times 420 = 336mm of HgHg

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