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NEET2003ChemistrySolutionsActual

Formation of a solution from two components can be considered as: (i) Pure solvent separated solvent molecules H ₁ (ii) Pure solute separated solute molecules, H ₂ (iii) Separated solvent and solute molecules solution, H ₃ Solution so formed will be ideal of:

Options

  1. AH _ soln = H ₁+ H ₂+ H ₃
  2. BH _ soln = H ₁+ H ₂- H ₃
  3. CH _ soln = H ₁- H ₂- H ₃
  4. DAH _ soln = AH ₃- AH ₁- AH ₂

Correct answer

A. H _ soln = H ₁+ H ₂+ H ₃

Step-by-step solution

So the enthalpy of solution can either be endothermic, exothermic or neither ( Hsolution =0) , depending on how much heat is required or release in each step. If Hsolution = 0 , then the solution is called an ideal solution and if Hsolution >0 or Hsolution < 0 , then these solutions are called non-ideal solutions. Related Theory The enthalpy of solution depends on the strengths of intermolecular forces of the solute and solvent. If the solution is ideal, and H solution =0 , then aligned & H_ solution = H₁+ H₂+ H₃=0

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