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NEET2004ChemistryThermodynamics (C)Actual

If the bond energies of H - H , Br - Br , and H - Br are 433,192 and 364 ~kJ / mol ⁻¹ respectively, the H ^ for the reaction H _ 2(g) + Br _ 2(g) 2 HBr _ (g) is:

Options

  1. A-261 ~kJ
  2. B+103 ~kJ
  3. C+261 ~kJ
  4. D-103 ~kJ

Correct answer

D. -103 ~kJ

Step-by-step solution

H - H + Br - Br 2 H - Br array rrr 433+192 & 2 & 364 =625 & =728 array Energy absorbed Energy released Net energy released = H _ R - H _ p =625-728=-103 ~kJ . Related Theory Fluorine has high bond energy because it is smallest among these molecules so it is tightly bonded to other atoms due to greater nuclear charge.

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