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NEET2004ChemistryThermodynamics (C)Actual

Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 ~K are -382.64 ~kJ ~mol ⁻¹ and -145.6 JK ⁻¹ ~mol ⁻¹ , respectively. Standard Gibbs energy change for the same reaction at 298 ~K is:

Options

  1. A-221.1 ~kJ ~mol ⁻¹
  2. B-339.3 ~kJ ~mol ⁻¹
  3. C-439.3 ~kJ ~mol ⁻¹
  4. D-523.2 ~kJ ~mol ⁻¹

Correct answer

B. -339.3 ~kJ ~mol ⁻¹

Step-by-step solution

G = H - T S =-382.64-298 ( -145.6 1000 ) aligned & =-382.64+43.38 & =-339.3 ~kJ ~mol ⁻¹ aligned Related Theory Free energy is an extensive quantity, but the standard free energy is an intensive quantity.

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