NEET2004ChemistryThermodynamics (C)Actual
Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 ~K are -382.64 ~kJ ~mol ⁻¹ and -145.6 JK ⁻¹ ~mol ⁻¹ , respectively. Standard Gibbs energy change for the same reaction at 298 ~K is:
Options
- A-221.1 ~kJ ~mol ⁻¹
- B-339.3 ~kJ ~mol ⁻¹
- C-439.3 ~kJ ~mol ⁻¹
- D-523.2 ~kJ ~mol ⁻¹
Correct answer
B. -339.3 ~kJ ~mol ⁻¹
Step-by-step solution
G = H - T S =-382.64-298 ( -145.6 1000 ) aligned & =-382.64+43.38 & =-339.3 ~kJ ~mol ⁻¹ aligned Related Theory Free energy is an extensive quantity, but the standard free energy is an intensive quantity.