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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Chemical Equilibrium

NTA Abhyas 2020 · Chemistry · Chemical Equilibrium

What is the equilibrium expression for the reaction P_ 4 (s) + 5 O_...

What is the equilibrium expression for the reaction
{\text{P}_{4}\left(\text{s}\right) + 5{\text{O}_{2} ( \text{g} ) ⇌ {\text{P}_{4}{\text{O}_{10} ( \text{s} )?

Options

  1. A{K}_{c} = \dfrac{\left[{P}_{4} {O}_{10}\right]}{\left[{P}_{4}\right]{\left[{O}_{5}\right]}^{5}}
  2. B{\text{K}_{\text{c}} = \dfrac{[ {\text{P}_{4}{\text{O}_{10} ]}{5\left[{\text{P}_{4}\right] [ {\text{O}_{2} ]}
  3. C{\text{K}_{\text{c}} = {\left[{\text{O}_{2}\right]}^{5}
  4. D{\text{K}_{\text{c}} = \dfrac{1}{{\left[{\text{O}_{2}\right]}^{5}}

Correct answer

D. {\text{K}_{\text{c}} = \dfrac{1}{{\left[{\text{O}_{2}\right]}^{5}}

Step-by-step solution

In the expression for equilibrium constant ( {\text{K}_{\text{p}}\text{o}\text{r}{\text{K}_{\text{c}} ) species in solid state are not written (i.e\text{i} . \text{e}., their molar concentrations are taken as 1)

{\text{P}_{4}\left(\text{s}\right) + 5{\text{O}_{2} ( \text{g} ) ⇌ {\text{P}_{4}{\text{O}_{10} ( \text{s} )

Thus, {\text{K}_{\text{c}} = \dfrac{1}{{\left[{\text{O}_{2}\right]}^{5}}
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