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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Chemical Equilibrium

NTA Abhyas 2020 · Chemistry · Chemical Equilibrium

For the reaction N _ 2 O _ 4 ⇌ 2N O _ 2(g) , the degree of...

For the reaction N2O4⇌2NO2(g){N}_{2}{O}_{4} ⇌ 2N{O}_{2\left(g\right)},thedegreeofdissociationof, the degree of dissociation of{N}_{2}{O}_{4}isis0.2atat1atm . Then the Kp{K}_{p} of 2NO2⇌N2O42N{O}_{2} ⇌ {N}_{2}{O}_{4} isFor the reaction N _ 2 O _ 4 ⇌ 2N O _ 2(g) , the degree of dissociation of N _ 2 O _ 4 is 0.2 at 1atm . Then the K _ p

Correct answer

6

Step-by-step solution

For the reaction N _ 2 O _ 4 ⇌ 2N O _ 2(g) , the degree of dissociation of N _ 2 O _ 4 is 0.2 at 1atm . Then the K _ p

Kp=[PNO2]2PN2O4{\text{K}}_{\text{p}} = \dfrac{{\left[{\text{P}}_{{\text{NO}}_{\text{2}}}\right]}^{2}}{{\text{P}}_{{\text{N}}_{2} {\text{O}}_{\text{4}}}}

Kp=4α21−α2p{\text{K}}_{\text{p}} = \dfrac{\text{4}{\alpha}^{2}}{1 - {\alpha}^{2}} \text{p}

⇒Kp=4×(0.2)21−(0.2)2=0.160.96⇒ {\text{K}}_{\text{p}} = \dfrac{4 \times {\left(0.2\right)}^{2}}{1 - {\left(0.2\right)}^{2}} = \dfrac{0.16}{0.96}

for2NO2⇌N2O4;Kp=0.960.16=6\text{for}2{\text{NO}}_{2} \overset{}{⇌} {\text{N}}_{\text{2}} {\text{O}}_{4} ; {\text{K}}_{\text{p}} = \dfrac{0.96}{0.16} = 6
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