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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Redox Reactions

NTA Abhyas 2020 · Chemistry · Redox Reactions

2.68 × 10 ^ - 3 moles of a solution containing an ion A^ n+ require...

2.68×10−32.68 \times {10}^{- 3} moles of a solution containing an ion An+A^{\text{n+}} require 1.61×10−1\text{1}\text{.61} \times {\text{10}}^{- 1} moles of~ MnO4−{MnO}_{4}^{-} ion for the oxidation of An+A^{\text{n+}} to AO3−{AO}_{3}^{-}~in acidic medium. What is the value of n?\text{n?}

Correct answer

2.00

Step-by-step solution

\left[{\text{A}}^{\text{n} +} \to \overset{+ 5}{\text{A}} {\text{O}_{3} {}^{-} + \left(5 - \text{n}\right){\text{e}}^{-}\right] \times 5,Oxidationhalfreaction<br/><br/>[MnO4−+8H++5e−→Mn2++4H2O]×(5−n),Oxidation half reaction<br /><br />\left[{MnO}_{4}^{-} + 8{H}^{+} + 5{e}^{-} \to {Mn}^{2 +} + 4{H}_{2}O\right] \times ( 5 - n ) ,Reduction half reaction

Applying reaction stoichiometry,

{\text{5 moles of A}}^{\text{n+}} = \left(\text{5-n}\right){\text{moles of MnO}_{4}^{-}
55-n=2.68×10−31.61×10−3=1.66=53\dfrac{\text{5}}{\text{5-n}} = \dfrac{\text{2.68} \times 1 {0}^{- 3}}{\text{1.61} \times {\text{10}}^{- 3}} = \text{1.66} = \dfrac{\text{5}}{\text{3}}
5−n=35 - \text{n} = 3
∴n=2∴ \text{n} = 2
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