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AIIMS 2014
Exam
AIIMS
Year
2014
Subject
Chemistry
Chapter
Solid State

AIIMS 2014 · Chemistry · Solid State

A forms h c p lattice and B are occupying 1 / 3^ rd of tetrahedral...

Aformsformsh c platticeandlattice andBareoccupying1/3rd are occupying 1 / 3^{\text{rd }} of tetrahedral voids, then the formula of compound is

Options

  1. AABA B
  2. BA3B2A_3 B_2
  3. CA2B3A_2 B_3
  4. DAB4A B_4

Correct answer

B. A3B2A_3 B_2

Step-by-step solution

Let no. of atoms of AA used in close packing=n=n Number of tetrahedral voids =2n=2 n Number of atoms of B=13×2n=23nB=\frac{1}{3} \times 2 n=\frac{2}{3} n A:B=n:23n=3:2A: B=n: \frac{2}{3} n=3: 2 Formula of the compound =A3B2=A_3 B_2
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