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AIIMS 2003
Exam
AIIMS
Year
2003
Subject
Chemistry
Chapter
Solid State

AIIMS 2003 · Chemistry · Solid State

What is the co-ordination number of sodium in Na_2 O ?

What is the co-ordination number of sodium in Na2O\mathrm{Na}_2 \mathrm{O} ?

Options

  1. A6
  2. B4
  3. C8
  4. D2

Correct answer

B. 4

Step-by-step solution

Na2O\mathrm{Na}_2 \mathrm{O} has antifluorite structure. O2−\mathrm{O}^{2-} ions constitute a ccp lattice and Na+\mathrm{Na}^{+}ions occupy the tetrahedral voids, each O2−\mathrm{O}^{2-} ion is in contact with 8Na+8 \mathrm{Na}^{+} ions and each Na+\mathrm{Na}^{+}ion is in contact with 4O2−4 \mathrm{O}^{2-} ions. Thus C.N. of sodium in Na2O=4\mathrm{Na}_2 \mathrm{O}=4.
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