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NTA Abhyas NEET2020Chemistryp Block Elements (Group 13 & 14)Practice

Methane is quite stable, whereas silane is unstable? Because -

Options

  1. AC — C bond energy is much greater than S i — S i bond energy
  2. BS i — H bond energy is much lower than C — H bond energy
  3. CS i has vacant p- orbitals which are more susceptible for nucleophilic attack
  4. DAll of above reasons

Correct answer

B. S i — H bond energy is much lower than C — H bond energy

Step-by-step solution

S i — H bond energy is 393 k J / m o l Whereas, C — H bond energy is 435 k J / m o l D C — C ⋍ 340 k J / m o l & D S i — S i ⋍ 368 k J / m o l C — C and S i — S i bond energies are comparable, while Si − H bond energy is lower than C − H bond energy, so methane is quite stable, whereas silane is unstable.

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