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NEET
Exam
NEET
Subject
Physics
Chapter
Atomic Physics

NEET · Physics · Atomic Physics

Given below are two statements: one is labelled as Assertion (A)...

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A): The kinetic energy of an electron in the first excited state of a hydrogen atom is four times its kinetic energy in the third excited state.

Reason (R): The kinetic energy of an electron in a hydrogen atom is inversely proportional to the square of the principal quantum number.

In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. ABoth (A) and (R) are correct and (R) is the correct explanation of (A)
  2. BBoth (A) and (R) are correct but (R) is not the correct explanation of (A)
  3. C(A) is correct but (R) is not correct
  4. D(A) is not correct but (R) is correct

Correct answer

A. Both (A) and (R) are correct and (R) is the correct explanation of (A)

Step-by-step solution

Reason (R) is correct: According to Bohr's model, the kinetic energy of an electron in the nthn^{\text{th}} orbit of a hydrogen atom is K=13.6n2 eVK = \dfrac{13.6}{n^2} \text{ eV}. Thus, K∝1n2K \propto \dfrac{1}{n^2}.

Assertion (A) is correct: The first excited state corresponds to the principal quantum number n1=2n_1 = 2, and the third excited state corresponds to n2=4n_2 = 4.

Using the relation from the Reason:
K1∝122=14K_1 \propto \dfrac{1}{2^2} = \dfrac{1}{4}
K2∝142=116K_2 \propto \dfrac{1}{4^2} = \dfrac{1}{16}

The ratio of their kinetic energies is K1K2=1/41/16=4\dfrac{K_1}{K_2} = \dfrac{1/4}{1/16} = 4.
Therefore, the kinetic energy in the first excited state is four times that in the third excited state.

Since the inverse-square relationship directly leads to the calculated ratio, (R) is the correct explanation of (A).

Answer: Both (A) and (R) are correct and (R) is the correct explanation of (A)
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