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NEETChemistryChemical Bonding and Molecular Structure

Match List I with List II List I List II A. XeF 4 I.See-saw B. SF 4 II. Square planar C. NH 4 + III. Bent T - shaped D. BrF 3 IV. Tetrahedral Choose the correct answer from the options given below :

Options

  1. AA - IV , B - III , C - II , D - I
  2. BA - II , B - I , C - III , D - IV
  3. CA - IV , B - I , C - II , D - III
  4. DA - II , B - I , C - IV , D - III

Correct answer

D. A - II , B - I , C - IV , D - III

Step-by-step solution

(A) XeF 4 : Xe has 4 bond pairs along with 2 lone pairs in the XeF 4 . Thus, the hybridisation of Xe is sp 3 d 2 . Now since it contains two lone pairs it will show square planar geometry. (B) SF 4 : The lone pair is an equatorial position, and there are two lone-pair—bond pair repulsions. Hence, it is more stable. So, the shape is described as a distorted tetrahedron, a folded square or a see-saw. (C) NH 4 + : In this case steric number = lone pair + sigma bond = 0 + 4 = 4. So, it is sp 3 hybridisation. There is n

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