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NEETChemistryChemical Bonding and Molecular Structure

Which of the following pairs of species have the same bond order, but one is diamagnetic and the other is paramagnetic?

Options

  1. AO ₂²⁻ and F ₂
  2. BO ₂^+ and N ₂^-
  3. CO ₂ and C ₂
  4. DB ₂ and O ₂

Correct answer

C. O ₂ and C ₂

Step-by-step solution

The bond order (BO) and magnetic nature of the given species are evaluated using Molecular Orbital Theory: 1) O ₂²⁻ (18 e^- ): BO = 1, diamagnetic. F ₂ (18 e^- ): BO = 1, diamagnetic. Both have the same BO and both are diamagnetic. 2) O ₂^+ (15 e^- ): BO = 2.5, paramagnetic. N ₂^- (15 e^- ): BO = 2.5, paramagnetic. Both have the same BO and both are paramagnetic. 3) O ₂ (16 e^- ): BO = 2, paramagnetic (due to two unpaired electrons in ^ * 2p orbitals). C ₂ (12 e^- ): BO = 2, diamagnetic (all electrons are paired in

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