Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
NEETChemistryChemical Bonding and Molecular Structure

Which of the following molecules has an expanded octet around its central atom and possesses a square planar geometry?

Options

  1. ASF ₄
  2. BBrF ₅
  3. CXeF ₄
  4. DPCl ₅

Correct answer

C. XeF ₄

Step-by-step solution

Let us evaluate the electron count and geometry for each molecule based on VSEPR theory: SF ₄ : Sulfur has 6 valence electrons. It forms 4 single bonds with F and has 1 lone pair. Total electrons around S = 4 2 + 2 = 10 (expanded octet). Geometry: See-saw. BrF ₅ : Bromine has 7 valence electrons. It forms 5 single bonds with F and has 1 lone pair. Total electrons around Br = 5 2 + 2 = 12 (expanded octet). Geometry: Square pyramidal. XeF ₄ : Xenon has 8 valence electrons. It forms 4 single bonds with F and has 2 lon

Practice Chemical Bonding and Molecular Structure on Quantrex Academy →

More from Chemical Bonding and Molecular Structure

Which of the following molecules shows sp ^3 d hybridisation? 2026Identify a pair of molecules having zero dipole moment. 2026Identify the correct decreasing order of lattice enthalpy for metal fluorides from following. 2026Which of the following bonds is expected to be the most polar? 2026Which of the following species is paramagnetic? 2026What is the number of bonding and antibonding electrons, respectively, in Li ₂ molecule? 2026What is the number of electrons in bonding molecular orbitals and antibonding molecular orbitals respectively in F ₂ molecule? 2026Identify the hybridization in BF ₃ molecule. 2026 Full Chemical Bonding and Molecular Structure list All NEET PYQs