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NEETChemistryChemical Bonding and Molecular Structure

The correct decreasing order of bond angles in the following hydrides is :

Options

  1. AH ₂ S > PH ₃ > NH ₃ > CH ₄
  2. BCH ₄ > PH ₃ > NH ₃ > H ₂ S
  3. CCH ₄ > NH ₃ > H ₂ S > PH ₃
  4. DCH ₄ > NH ₃ > PH ₃ > H ₂ S

Correct answer

D. CH ₄ > NH ₃ > PH ₃ > H ₂ S

Step-by-step solution

According to VSEPR theory, the presence of lone pairs on the central atom causes greater repulsion than bond pairs, compressing the bond angle. CH ₄ has 0 lone pairs ( 109.5^ ), while NH ₃ has 1 lone pair ( 107^ ). Thus, CH ₄ > NH ₃ . Moving down a group (from N to P or O to S), the electronegativity of the central atom decreases and its size increases. This causes the bond pairs to move further away from the central atom, decreasing the bond pair - bond pair repulsion and significantly reducing the bond angle. Thu

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