NEETChemistryChemical Bonding and Molecular Structure
The correct decreasing order of bond angles in the following hydrides is :
Options
- AH ₂ S > PH ₃ > NH ₃ > CH ₄
- BCH ₄ > PH ₃ > NH ₃ > H ₂ S
- CCH ₄ > NH ₃ > H ₂ S > PH ₃
- DCH ₄ > NH ₃ > PH ₃ > H ₂ S
Correct answer
D. CH ₄ > NH ₃ > PH ₃ > H ₂ S
Step-by-step solution
According to VSEPR theory, the presence of lone pairs on the central atom causes greater repulsion than bond pairs, compressing the bond angle. CH ₄ has 0 lone pairs ( 109.5^ ), while NH ₃ has 1 lone pair ( 107^ ). Thus, CH ₄ > NH ₃ . Moving down a group (from N to P or O to S), the electronegativity of the central atom decreases and its size increases. This causes the bond pairs to move further away from the central atom, decreasing the bond pair - bond pair repulsion and significantly reducing the bond angle. Thu