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NEET2010ChemistryChemical Bonding and Molecular StructureActual

The shape and hybridisation of some xenon oxyfluorides are given. Choose the wrong set.

Options

  1. AXeOF ₂- T -Shape-sp ^3 d
  2. BXeOF ₄- Square pyramidal- s p^3 d^2
  3. CXeO ₂ ~F ₂- Distorted trigonal bipyramidal-sp p^3 d
  4. DXeO ₃ ~F ₂- Octahedral -s p^3 d

Correct answer

D. XeO ₃ ~F ₂- Octahedral -s p^3 d

Step-by-step solution

The structure of No. of lone pair of X e=0 and no. of bond pair =5 Hybridisation of Xe =s p^3 d Hence, shape of XeO ₃ ~F ₂ should be trigonal bipyramidal and not octahedral.

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