NEET2004ChemistryChemical Bonding and Molecular StructureActual
The ONO angle is maximum in
Options
- ANO ₃⁻
- BNO ₂⁻
- CNO ₂
- DNO ₂⁺ .
Correct answer
D. NO ₂⁺ .
Step-by-step solution
The nitrate ion has three resonance structure, with the double bond on a different oxygen for each. In all resonance structures the nitrogen has three bonds, therefore, its hybridisation is s p^2 . Each of the oxygen atoms also has s p^2 hybridisation, since the hybridisation is determined by the resonance structure with the double bond, where the oxygen has a double bond and two lone pairs. The actual geometry of the polyatomic ion is trigonal planar with bond angles of 120^ . NO ₂⁻: 18 electrons; ideal geometry t