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NEET2001ChemistryChemical Bonding and Molecular StructureActual

Which of the following option w.r.t. increasing bond order is correct ?

Options

  1. ANO < C ₂ < O ₂⁻ < He ₂⁺
  2. BC ₂ < NO < He ₂⁺ < O ₂⁻
  3. CHe ₂⁺ < O ₂⁻ < NO < C ₂
  4. DHe ₂⁺ < O ₂⁻ < C ₂ < NO .

Correct answer

D. He ₂⁺ < O ₂⁻ < C ₂ < NO .

Step-by-step solution

Bond order of the molecules : O ₂⁻: K K( 2 s)^2 ( ₂ * )^2 ( 2 p_ z )^2 ( 2 p_ x )^2 ( 2 p_ y )^2 ( ^* 2 p_x )^2 ( ^* 2 p_y )^1 Bond order of O ₂⁻= 1 2 (8-5)=1.5 He ₂⁺:( 1 s)^2 ( ^* 1 s )^1 Bond order of He ₂⁺= 1 2 (2-1)=0.5 C ₂: K K( 2 s)^2 ( ^* 2 s )^2 ( 2 p_ x )^2 ( 2 p_ y )^2 Bond order = 1 2 (6-2)=2.0 NO : K K( 2 s)^2 ( ^* 2 s )^2 ( 2 p_ z )^2 ( 2^2 p_ x )^2 ( 2^2 p_ y )^2 ( * 2 p_ x )^1 Bond order = 1 2 (8-3)=2.5

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