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NEET2009ChemistryChemical Bonding and Molecular StructureActual

H - O - H bond angle in H ₂ O is 104.5^ and not 109^ 28^ because of

Options

  1. Alone pair-lone pair repulsion
  2. Blone pair-bond pair repulsion
  3. Cbond pair-bond pair repulsion
  4. Dhigh electronegativity of oxygen

Correct answer

A. lone pair-lone pair repulsion

Step-by-step solution

The hybridisation of oxygen in water molecule is s p^3 . So, water molecule must be tetrahedral and have bond angle 109^ 28^ . But due to the presence of two lone pair of electrons on oxygen atom (repulsion between lone pair-lone pair) the bond angle decreases about 104.5^ and the geometry becomes distorted tertrahedral or V-shaped.

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