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NEETChemistryGeneral Organic Chemistry

Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens?

Options

  1. ANitric acid is added to decompose NaCN to HCN and Na 2 S to H 2 S and to expel these gases. That is, if any ni
  2. BNitric acid is added to increase the pH of the solution, which enhances the solubility of halide precipitates
  3. CNitric acid is added to react with any remaining halogens in the sodium extract, converting them to soluble ni
  4. DNitric acid is added to react with silver nitrate, forming a complex that improves the sensitivity of the test

Correct answer

A. Nitric acid is added to decompose NaCN to HCN and Na 2 S to H 2 S and to expel these gases. That is, if any ni

Step-by-step solution

Correct Option is : (A) Nitric acid is added to decompose NaCN to HCN and Na 2 S to H 2 S and to expel these gases. That is, if any nitrogen and sulphur are present in the form of NaCN and Na 2 S, then they are removed and only halogens are available for testing.

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