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General Organic Chemistry — NEET UG Chemistry PYQs

1,091 previous year questions from General Organic Chemistry with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

1,091 questionsChemistrySolutions on every page
1

Identify the overlapping orbitals involved in hyperconjugation from following.

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2

What is the IUPAC name of ( CH ₃)₂ CH-COOH ?

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3

What is the IUPAC name of the following compound?

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4

CH ₃ -CH=CH-CH ₂ -COOH What is the IUPAC name of the above compound ?

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5

What is IUPAC name of the following organic compound?

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6

Which of the following exhibits - I effect?

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7

Which of the following statement is NOT correct about a racemic mixture?

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8

What type of isomerism is found in but-2-ene?

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9

How many primary amine isomeric forms are possible for the formula C ₄ H ₁₁ N ?

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10

Identify free radical inhibitor from following. (A) (B) O ₂ (C) (D) CrO ₃ Choose the correct answer from the options given below.

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11

The delocalization of electrons due to overlap between p-orbital and sigma bond is called.

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12

Which of the following factors is associated with optical activity of a molecule?

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13

What is IUPAC name of acrylic acid?

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14

Which of the following is heterocyclic aromatic compound?

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15

Which among the following is false statement for enantiomers?

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16

What is IUPAC name of Isoprene?

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17

The IUPAC name of compound

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18

Identify the alkane having two secondary carbon atoms.:

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19

The IUPAC name of Neo-pentyl chloride is _____

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20

Identify the correct order of the priority of the following functional group.

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21

The dihedral angle in the staggered conformation of CH ₃ CH ₃ is

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22

What is IUPAC name of ( CH ₃)₃ CBr ?

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23

Compare the relative stability of given carbocations. CH ₃ - + C -(CH ₃)₂ (I) CH ₃ - + C H-CH ₃ (II) CH ₃ - + C H ₂ (III)

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24

Which of the following is a gas at room temperature ?

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25

Which of the following instruments is used to find out absorption of functional groups?

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26

Identify the IUPAC name of the compound.

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27

Which of the following is Not a Freon?

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28

Which of the following formula of the third higher Homologue of CH ₃ -CH ₂ -COOH ?

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29

The following carbocation is stabilized by the interaction of the empty p orbital with

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30

The pair of molecules that are metamers among the following is :

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31

During Lassaigne's test, the elements present in an organic compound are converted from :

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32

The correct IUPAC name of the following compound is :

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33

Arrange the following compounds in the increasing order of polarity A. CH ₃ CH ₂ OCH ₂ CH ₃ B. CH ₃ CH ₂ OH C. CH ₃ COCH ₃ D. CH ₃ COOH Choose the correct answer from the options g

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34

Which one of the following compounds can exist as cis-trans isomers?

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35

Which one of the following reactions does NOT belong to "Lassaigne's test" ?

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36

Among the given compound I-III, the correct order of bond dissociation energy of C - H bond marked with * is :-

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37

Match List-I with List-II array |l|l|l|l| & List-I (Mixture) & & List-II (Method of Separation) A. & CHCl ₃+ C ₆ H ₅ NH ₂ & I. & Distillation under reduced pressure B. & Crude oil

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38

The correct IUPAC name of the compound

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39

On complete combustion, 0.3 g of an organic compound gave 0.2 g of CO ₂ and 0.1 g of H ₂ O . The percentage composition of carbon and hydrogen in the compound, respectively is:

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40

Methyl group attached to a positively charged carbon atom stabilizes the carbocation due to

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41

On heating, some solid substances change from solid to vapour state without passing through liquid state. The technique used for the purification of such solid substances based on

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42

Given below are two statements: Statement I : The boiling point of three isomeric pentanes follows the order n-pentane isopentane neopentane Statement II : When branching increases

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43

The most stable carbocation among the following is :

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44

A compound with a molecular formula of C ₆ H ₁₄ has two tertiary carbons. Its IUPAC name is :

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45

A steam volatile organic compound which is immiscible with water has a boiling point of 250^ C . During steam distillation, a mixture of this organic compound and water will boil :

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46

Match List-I with List-II. ( array |c|l|c|l| & List-I & & List-II & (Mixtures/Sample) & & (Technique used for purification) (A) & Glycerol from spent lye & (I) & Steam distillation

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47

Given below are two statements: Statement I: In an organic compound, when inductive and electromeric effects operate in opposite directions, the inductive effect predominates. Stat

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48

In Lassaigne's extract of organic compound both nitrogen and sulphur are present, which gives blood-red colour with Fe 3 + due to the formation of

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49

Which amongst the following will be most readily dehydrated under acidic conditions?

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50

The given compound is an example of

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51

(i) (ii) (iii) (iv) (v) (vi) (vii) The number of compounds/species which obey Huckel's rule is _____

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52

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Chlorine is an electron withdrawing group but it is ortho,

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53

Which compound amongst the following is not an aromatic compound?

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54

The Kjeldahl's method for the estimation of nitrogen can be used to estimate the amount of nitrogen in which one of the following compounds?

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55

The incorrect statement regarding chirality is :

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56

The correct IUPAC name of the following compound is:

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57

Which of the following is the most stable carbocation?

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58

The correct structure of 2 ,   6 - Dimethyldec- 4 -ene is:

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59

The compound which shows metamerism is:

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60

Dihedral angle of least stable conformer of ethane is:

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61

A tertiary butyl carbocation is more stable than a secondary butyl carbocation because of which of the following?

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62

Paper chromatography is an example of

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63

A liquid compound (x) can be purified by steam distillation only if it is

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64

During nitration of benzene, the attacking electrophile is

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65

Write the IUPAC name of given structure

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66

Which of the following amino acid is optically inactive?

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67

Which can not behave as a nucleophile for S _ N 2 reaction?

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68

Which method is used to find halogen in organic compound?

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69

Write IUPAC name of the following

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70

The most stable carbocation, among the following is

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71

The correct order of the basis strength of methyl substituted amines in aqueous solution is:

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72

The compound that is most difficult to protonate is:

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73

Among the following, the non-aromatic heterocyclic compound is

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74

Which of the following compound can exhibit tautomerism?

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75

In Kjeldahl's method, the nitrogen present in an organic compound is quantitatively converted into

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76

The pair of structures given below represents

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77

Relative stabilities of the following carbocations will be in the order

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78

Which of the following carbocations is expected to be the most stable?

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79

Nitration of aniline in strong acidic medium also gives m -nitroaniline because:

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80

Which of the following is correct with respect to - I effect of the substituent? ( R = alkyl group)

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81

Which of the following is the correct IUPAC name?

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82

Which of the following sodium compound/compound(s) are formed when an organic compound containing both nitrogen and sulphur is fused with sodium?

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83

The most stable carbonium ion among the following is

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84

Which one of the following is the most acidic compound?

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85

The correct statement regarding electrophile is,

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86

The most suitable method of separation of 1 : 1 mixture of ortho and para-nitrophenol is:

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87

With respect to the conformers of ethane, which of the following statements is true?

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88

The IUPAC name of the compound is ________.

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89

Consider the following structures. Choose the correct statement regarding the above structures.

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90

Duma's method involves the determination of nitrogen content in the organic compound in the form of

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91

In which of the following molecules, all atoms are coplanar?

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92

Which among the given molecules can exhibit tautomerism ?

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93

The correct order of strengths of carboxylic acids is

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94

The correct statement regarding a carbonyl compound with a hydrogen atom on its alpha carbon, is:

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95

The correct statement regarding the basicity of aryl amines is:

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96

The pair of electron in the given carbanion, C H 3 C ≡ C ⊖   is present in which of the following orbitals?

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97

In pyrrole, the electron density is maximum on

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98

The correct statement regarding the comparison of staggered and eclipsed conformations of ethane, is:

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99

Which of the following biphenyls is optically active?

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100

The suitable reaction steps to carry out the following transformation is

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101

The major product P will be

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102

For carbanion Stability order will be

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103

What is product of the following sequence of reactions?

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104

The aqueous solution of an unknown sodium salt gives the following reactions. I. It decolourises a solution of iodine in potassium iodide. II. It gives white turbidity with dil. HC

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105

What is correct about the following structure?

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106

Which of the following statements is not correct for a nucleophile?

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107

Two possible stereo-structures of C H 3 C H O H C O O H , which are optically active, are called:

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108

In Duma's method for estimation of nitrogen, 0.25 g of an organic compound gave 40 mL of nitrogen collected at 300 K temperature and 725 mm pressure. If the aqueous tension at 300

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109

Consider the following compounds Hyperconjugation occurs in:

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110

Which of the following is the most correct electron displacement for a nucleophile reaction to take place?

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111

Given, Which of the given compounds can exhibit tautomerism?

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112

In which of the following compounds, the C - C l bond ionization shall give most stable carbonium ion?

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113

The number of structural isomers possible from the molecular formula C 3 H 9 N is:

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114

In Duma's method of estimation of nitrogen, 0.35 g of an organic compound gave 55 mL of nitrogen collected at 300 K temperature and 715 mm pressure. The percentage composition of n

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115

Which of the following is not a resonating form of benzaldehyde?

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116

Which of the following compounds gives carbylamine test?

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117

Which of the following will be most stable diazonium salt R N 2 + X - ?

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118

In the Kjedahl's method for estimation of nitrogen present in soil sample, ammonia evolved from 0.75 g of sample neutralized 1 0 m l of 1 M   H 2 S O 4 The percentage of n

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119

Which of the following compounds will undergo racemisation when solution of K O H hydrolyses? (i) (ii) C H 3 C H 2 C H 2 C l (iii) (iv)

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120

Which one of the following acts as a nucleophile?

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