NEETChemistryGeneral Organic Chemistry
How many of the following compounds exhibit geometrical isomerism? (I) But-2-ene (II) 1,1-Dichloroethene (III) 1,3-Dimethylcyclopentane (IV) 2-Methylbut-2-ene (V) 1,2-Dimethylcyclohexane
Options
- A2
- B3
- C4
- D5
Correct answer
B. 3
Step-by-step solution
For geometrical isomerism (GI) in alkenes, each carbon atom of the double bond must be bonded to two different atoms or groups. For GI in cycloalkanes, at least two sp ^3 hybridized ring carbons must each be bonded to two different atoms or groups. (I) But-2-ene: CH₃-CH=CH-CH₃ . Each double-bonded carbon is attached to a hydrogen atom and a methyl group. It exhibits GI. (II) 1,1-Dichloroethene: CCl₂=CH₂ . One double-bonded carbon is attached to two identical chlorine atoms. It does not exhibit GI. (III) 1,3-Dimethy