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NEETChemistryGeneral Organic Chemistry

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Toluene undergoes electrophilic aromatic substitution faster than benzene. Reason (R): The methyl group in toluene increases the electron density in the benzene ring predominantly through its +I (inductive) effect, which outweighs the hyperconjugation effect. In the light of the above statements, c

Options

  1. ABoth Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A).
  2. BBoth Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of Assertion (A).
  3. CAssertion (A) is true but Reason (R) is false.
  4. DAssertion (A) is false but Reason (R) is true.

Correct answer

C. Assertion (A) is true but Reason (R) is false.

Step-by-step solution

Assertion (A) is true: Toluene has a methyl group attached to the benzene ring, which acts as an electron-donating group. This increases the electron density on the ring, making it more reactive towards electrophilic aromatic substitution than benzene. Reason (R) is false: The methyl group exerts both a +I (inductive) effect and a hyperconjugation effect. However, hyperconjugation (a permanent delocalisation of -electrons into the -system) is a stronger effect than the inductive effect and is predominantly responsi

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