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NEETChemistryGeneral Organic Chemistry

What is the minimum number of carbon atoms required for an aliphatic, non-cyclic ketone to exhibit metamerism?

Options

  1. A5
  2. B3
  3. C4
  4. D6

Correct answer

A. 5

Step-by-step solution

Metamerism arises due to different alkyl chains on either side of a polyvalent functional group. For ketones, the functional group is the carbonyl group ( - CO - ), which is divalent. Let us check the homologous series of aliphatic ketones: With 3 carbon atoms: CH ₃- CO - CH ₃ (Propanone). No other arrangement of alkyl groups around the carbonyl carbon is possible. With 4 carbon atoms: CH ₃- CO - CH ₂ CH ₃ (Butan-2-one). No other arrangement is possible. With 5 carbon atoms: The alkyl groups can be a methyl and a p

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