NEETChemistryGeneral Organic Chemistry
What is the minimum number of carbon atoms required for an aliphatic, non-cyclic ketone to exhibit metamerism?
Options
- A5
- B3
- C4
- D6
Correct answer
A. 5
Step-by-step solution
Metamerism arises due to different alkyl chains on either side of a polyvalent functional group. For ketones, the functional group is the carbonyl group ( - CO - ), which is divalent. Let us check the homologous series of aliphatic ketones: With 3 carbon atoms: CH ₃- CO - CH ₃ (Propanone). No other arrangement of alkyl groups around the carbonyl carbon is possible. With 4 carbon atoms: CH ₃- CO - CH ₂ CH ₃ (Butan-2-one). No other arrangement is possible. With 5 carbon atoms: The alkyl groups can be a methyl and a p