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NEETChemistryGeneral Organic Chemistry

The correct decreasing order of the basic strength of ethyl substituted amines and ammonia in aqueous solution is:

Options

  1. A( C ₂ H ₅)₂ NH > C ₂ H ₅ NH ₂ > ( C ₂ H ₅)₃ N > NH ₃
  2. B( C ₂ H ₅)₂ NH > ( C ₂ H ₅)₃ N > C ₂ H ₅ NH ₂ > NH ₃
  3. C( C ₂ H ₅)₃ N > ( C ₂ H ₅)₂ NH > C ₂ H ₅ NH ₂ > NH ₃
  4. DNH ₃ > C ₂ H ₅ NH ₂ > ( C ₂ H ₅)₃ N > ( C ₂ H ₅)₂ NH

Correct answer

B. ( C ₂ H ₅)₂ NH > ( C ₂ H ₅)₃ N > C ₂ H ₅ NH ₂ > NH ₃

Step-by-step solution

In aqueous solution, the basic strength of amines depends on the combined effect of the inductive effect (+I), solvation (hydrogen bonding with water), and steric hindrance. For ethyl substituted amines, the larger size of the ethyl group compared to the methyl group causes steric hindrance to play a more significant role, altering the balance between solvation and the +I effect. The resulting order of basicity for ethylamines in aqueous solution is secondary > tertiary > primary > ammonia. Therefore, the correct d

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