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NEET2011ChemistryGeneral Organic ChemistryActual

The correct decreasing order of p K_a is

Options

  1. AII > IV > I > III
  2. BIV > II > III > I
  3. CIII > II > IV > I
  4. DIV > I > II > III

Correct answer

A. II > IV > I > III

Step-by-step solution

Weaker acids have higher p K_a - OCH ₃ at meta-position exerts only -I effect, hence increase the acidity. -I effect order : - NO ₂>- OCH ₃>- Cl . - CH ₃ has +I effect. So order is (1).

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