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NEET2008ChemistryGeneral Organic ChemistryActual

Assertion : Anilinium chloride is more acidic than ammonium chloride. Reason : Anilinium chloride is resonance stabilised.

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of assertion.
  2. BIf both assertion and reason are true but reason is not the correct explanation of assertion.
  3. CIf assertion is true but reason is false.
  4. DIf both assertion and reason are false.

Correct answer

C. If assertion is true but reason is false.

Step-by-step solution

Aniline is weaker base than ammonium chloride. In NH ₄ Cl or aliphatic amines, nonbonding electron pair of N is localised and is fully available for coordination with a proton. aligned & C ₆ H ₅ NH ₃^ C ₆ H ₅ NH ₂+ H ⁺ & (stronger acid) (weaker-conjugate base) & aligned (stronger acid) (weaker-conjugate base) On the other hand, in aniline and other aromatic amines, the non-bonding electron pair is delocalised into benzene ring by resonance.

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